Reference of 33332-25-1, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 33332-25-1, Name is Methyl 5-chloropyrazine-2-carboxylate, SMILES is ClC1=CN=C(C=N1)C(=O)OC, belongs to Pyrazines compound. In a article, author is Benecke, Jannik, introduce new discover of the category.
A Flexible and Porous Ferrocene-Based Gallium MOF with MIL-53 Architecture
A new gallium based metal-organic framework, denoted as Ga-MIL-53-FcDC, with the chemical formula [Ga(OH)(FeC12H8O4)] was synthesized using the ferrocene containing linker molecule 1,1′-ferrocenedicarboxylic acid (H(2)FcDC, FeC12H10O4). The porous nature of the compound could be confirmed by nitrogen sorption and a specific surface area of 270 m(2)/g was determined. The persistence of the ferrocene complex inside the structure was confirmed by Mossbauer-, EPR and UV/VIS-spectroscopy. Ga-MIL-53-FcDC shows structural flexibility depending on which guest molecule is located in the pores of the compound. The mechanism of structural flexibility was analyzed by means of powder X-ray diffraction adsorbing pyrazine or iodine. The flexibility of the crystal structure can be attributed to the torsion of the GaO6 octahedra in the IBU respective to each other and the torsion of the carboxylate groups of FcDC(2-) relative to the aromatic ring.
Reference of 33332-25-1, The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 33332-25-1 is helpful to your research.