Time-resolved electron paramagnetic resonance investigation of photochemical reactions. Hydrogen abstraction in azaaromatics and carbonyls was written by Yamauchi, Seigo;Hirota, Noboru. And the article was included in Journal of Physical Chemistry in 1984.Related Products of 322-46-3 This article mentions the following:
Transient ESR spectra were observed for the intermediate radicals in the photoinduced H abstractions of azaarom. mols. and carbonyls in Me2CHOH. Temperature dependence was examined at -10 to -90°. The intermediate radicals are assigned from the spectra with partially resolved hyperfine structures. The precursory excited states for the reactions are determined from the signal polarities, and their properties are discussed in terms of the possible CIDEP mechanisms. The reactions occur from the T1(nπ*) states with neg. D values or the T1(ππ*) states with pos. D in the cases of azaaroms. In aromatic carbonyls the reactions occur from the T1(nπ*) or T2(nπ*) states with neg. D values, while in aliphatic carbonyls, from the T1(nπ*) states with pos. D values. In the experiment, the researchers used many compounds, for example, Pyrido[2,3-b]pyrazine (cas: 322-46-3Related Products of 322-46-3).
Pyrido[2,3-b]pyrazine (cas: 322-46-3) belongs to pyrazine derivatives. Pyrazine heterocycles and their benzo derivatives possess many interesting properties, including chemical reactivity profiles, and have diverse applications in total synthesis, medicine, chemical biology, materials, dyes, and imaging. Substituted pyrazines have been found as subunits of multiple synthetically constructed therapeutic agents, as well as several natural products.Related Products of 322-46-3