Efficient quasi-solid-state dye-sensitized solar cells based on organic sensitizers containing fluorinated quinoxaline moiety was written by Jia, Xiaowei;Zhang, Weiyi;Lu, Xuefeng;Wang, Zhong-Sheng;Zhou, Gang. And the article was included in Journal of Materials Chemistry A: Materials for Energy and Sustainability in 2014.Recommanded Product: 5,8-Dibromoquinoxaline This article mentions the following:
Two novel organic sensitizers (FNE55 and FNE56) containing a 6,7-difluoroquinoxaline moiety were designed and synthesized for quasi-solid-state dye-sensitized solar cells (DSSCs). For comparison, an organic dye, FNE54, without fluorine has also been synthesized. The effects of the introduction of fluorine on the absorption, electrochem., and photovoltaic properties have been systematically investigated. Upon the incorporation of fluorine in the quinoxaline unit, the electron-withdrawing ability is strengthened, which results in the enhanced push-pull interactions and thus narrows the energy band gap. The absorption maximum wavelength in toluene solution bathochromically shifts from 504 nm for FNE54 to 511 nm for FNE55, and further to 525 nm for FNE56. However, although the lowest unoccupied MOs (LUMOs) are lowered down after the introduction of fluorines, the driving force for the photo-excited electrons from their excited states to the semiconductor conduction band is still sufficient. Consequently, the quasi-solid-state DSSC based on FNE56 exhibits a highest power conversion efficiency of 8.2%, which is 37% higher than that for FNE54 based quasi-solid-state DSSCs. In the experiment, the researchers used many compounds, for example, 5,8-Dibromoquinoxaline (cas: 148231-12-3Recommanded Product: 5,8-Dibromoquinoxaline).
5,8-Dibromoquinoxaline (cas: 148231-12-3) belongs to pyrazine derivatives. Pyrazinesare six-membered aromatic heterocyclic organic compounds with two nitrogen atoms at 1,4-positions. Pyrazine is a weaker base (pKb = 13.4) than pyridine (pKb = 8.8), pyrimidine (pKb = 12.7). Pyrazines are chemical compounds (technically called “methoxypyrazines”) found in grape skin and stems that are responsible for many “green” flavors in wine. Levels of pyrazines are dependent on viticultural practices, climate, and grape variety.Recommanded Product: 5,8-Dibromoquinoxaline