Muralirajan, Krishnamoorthy published the artcileExploring the Structure and Performance of Cd-Chalcogenide Photocatalysts in Selective Trifluoromethylation, Name: 2,3,5-Trimethylpyrazine, the main research area is trifluoromethylated arene oxindole alkene preparation photochem; heteroarene alkene selective trifluoromethylation cadmium selenide catalyst.
The field of heterogeneous photoredox catalysis has grown substantially and impacted organic synthesis because of the affordability and reusability of catalysts. This study reports radical trifluoromethylation with Cd-chalcogenide semiconductors. Cd semiconductors, particularly CdSe, are readily available, com., visible-light-responsive, heterogeneous photocatalysts. The potential of readily available Cd semiconductors, particularly CdSe, is confirmed by their increased photocatalytic activity toward trifluoromethylation with various substrates, such as (hetero)arenes and vinylic amides/acids, via addition, cyclization, and decarboxylation under visible light. The economic significance of this strategy is also highlighted through the scalable synthesis of biol. active mols. followed by catalyst reuse. Moreover, these catalysts are relatively inexpensive compared with transition metal-based homogeneous photocatalysts, presently used in organic synthesis.
ACS Catalysis published new progress about Cyclization. 14667-55-1 belongs to class pyrazines, name is 2,3,5-Trimethylpyrazine, and the molecular formula is C7H10N2, Name: 2,3,5-Trimethylpyrazine.