Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, European Journal of Organic Chemistry called Application of Flow Chemistry to the Selective Reduction of Esters to Aldehydes, Author is Munoz, Juan de M.; Alcazar, Jesus; de la Hoz, Antonio; Diaz-Ortiz, Angel, which mentions a compound: 118994-89-1, SMILESS is O=C(C1=CN=CO1)OCC, Molecular C6H7NO3, Recommanded Product: 118994-89-1.
The reduction of esters to aldehydes is an important transformation in organic chem. and several reducing agents have been described. However, the use of this reaction in medicinal and natural product chem. is limited due to the instability of the intermediates and the high reactivity of the reaction products. In the current article, the general and selective reduction of esters with lithium diisobutyl-tert-butoxyaluminum hydride (LDBBA) in flow is reported. This reagent allows esters to be reduced in the presence of different functional groups, including those considered to be of similar or higher reactivity.
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