Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 591-54-8, is researched, SMILESS is C1=CN=CN=C1N, Molecular C4H5N3Journal, Energy Conversion and Management called Effects of demineralization on the composition of microalgae pyrolysis volatiles in py-GC-MS, Author is Niu, Qi; Ghysels, Stef; Wu, Nannan; Rousseau, Diederik P. L.; Pieters, Jan; Prins, Wolter; Ronsse, Frederik, the main research direction is inorganic element microalgae pyrolysis volatile demineralization Nannochloropsis gaditana.Quality Control of 4-Aminopyrimidine.
This study compared the volatiles distribution in anal. scale pyrolysis (py-GC-MS) of Nannochloropsis gaditana (marine microalgae) and Scenedesmus almeriensis (freshwater microalgae) and their demineralized counterparts. The role of inorganic elements and their removal via ultrasonic treatment, water washing and (in)organic acid leaching were elucidated. Principal component anal. (PCA) and gray relational anal. were applied to analyze the pyrolysis volatiles distribution and demonstrate the influence of inorganic elements in pyrolysis, resp. Demineralization affects (breaks down) the chem. structure of carbohydrates, followed by (to a lesser extent) proteins and lipids. Acid leaching promoted hydrolysis and suppressed the catalytic effect associated to inorganic elements in subsequent pyrolysis, compared to ultrasonic treatment and water washing. Elements like K and Na had a larger catalytic influence on microalgae pyrolysis than Ca and Mg. The composition and pyrolytic formation mechanism of major product groups at 500°C were studied, including anhydrosugars, phenolics, furans, carboxylic acids, alcs., aliphatic hydrocarbons, aromatic hydrocarbons, N-heterocyclic compounds, nitriles and amides. The results indicate that demineralization shows pos. effects on fast pyrolysis of microalgae: (1) by disrupting the cell wall and releasing the lipids and cellular contents. Based on the py-GC-MS peak area normalized to sample mass, the relative contribution of hydrocarbons in the pyrolysis vapors increased from 25.5% (NG: Nannochloropsis gaditana) to 32.1% (NG-HCl: Nannochloropsis gaditana, HCl treated), and from 16.1% (SA: Scenedesmus almeriensis) to 22.4% (SA-HCl: Scenedesmus almeriensis, HCl treated); (2) by decreasing the relative yields in O-containing compounds resulting from the suppressed catalytic effects of alkali and alk. earth metals (53.3% (NG) to 37.1% (NG-HCl), 57.5% (SA) to 47.8% (SA-HCl)) that would otherwise have been present in non-demineralized microalgae feedstock. The effects of demineralization on the denitrogenation of pyrolysis vapors were not that obvious. Suggestions for potential full scale applications have been proposed.
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