Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 118994-89-1, is researched, Molecular C6H7NO3, about A general route to the Streptomyces-derived inthomycin family: the first synthesis of (+)-inthomycin B, the main research direction is asym synthesis inthomycin B Stille coupling palladium catalyst; Stille coupling stannyl diene oxazole vinyl iodide; Kiyooka ketene acetal amino acid derived oxazaborolidinone directed aldol.Quality Control of Ethyl oxazole-5-carboxylate.
A concise, convergent and stereocontrolled synthesis of (+)-inthomycin B (I), based on the Stille coupling of a stannyl-diene with an oxazole vinyl iodide unit, is described. The asym. center was introduced using the Kiyooka ketene acetal/amino acid-derived oxazaborolidinone procedure.
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