Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 118994-89-1, is researched, Molecular C6H7NO3, about The syntheses of rac-inthomycin A, (+)-inthomycin B and (+)-inthomycin C using a unified synthetic approach, the main research direction is asym synthesis inthomycin B C Mukaiyama aldol reaction; Stille coupling reaction asym synthesis inthomycin A B C.Electric Literature of C6H7NO3.
The Stille coupling between a common oxazole vinyl iodide and stereodefined stannyl-diene units is described as the cornerstone of a unified synthetic route to the inthomycin family of bioactive Streptomyces metabolites. This procedure has been utilized to prepare (+)-inthomycin B (I) and (+)-inthomycin C (II) for the first time; in these examples the stereogenic center was introduced using the Kiyooka ketene acetal/amino acid-derived oxazaborolidinone variant of the Mukaiyama aldol reaction. In addition, a convenient preparation of rac-inthomycin A (III) is described based on the same strategy.
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