Quality Control of Pyrazine-2-carboxylic acid. Recently I am researching about FLUORESCENCE; SILVER; SURFACE, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21875125, 21561023]; Natural Science Foundation of Inner Mongolia Autonomous Region of China [2017JQ03]; Scientific Research Project of Inner Mongolia Autonomous Region Higher Education Institutions [NJZY17455]; Program of High-level Talents of Inner Mongolia University [21300-5155104]; Scientific Research Project of Jining Normal University [jsky2018024]. Published in ELSEVIER SCIENCE SA in LAUSANNE ,Authors: Zhao, YF; Wang, AL; Kang, J; Chu, HB; Zhang, HX; Zhao, YL. The CAS is 98-97-5. Through research, I have a further understanding and discovery of Pyrazine-2-carboxylic acid
Metal-enhanced luminescence (MEL) via Ag@SiO2 nanoparticles provides a promising strategy for the superior luminescence of lanthanide complexes. However, because of the delicate structure of the composites of Ag@SiO2 and complexes, it remains a great challenge to achieve the ideal MEL effect. Herein, five types of Ag@SiO2 nanoparticles with distinct core sizes (100 and 46 nm) and varied silica shell thickness (3, 24, 32, 52 and 55 nm) were prepared. Four kinds of lanthanide complexes RE(BA)(3)center dot H2O and RE(pyca)(3)center dot 2H(2)O (RE = Eu and Tb, BA = benzoate, pyca = 2-pyrazine carboxylate) were synthesized. A series of REL3-Ag@SiO2 (L = BA(-), pyca(-)) composite nanoparticles were prepared through the interaction of the Ag@SiO2 nanoparticles and the complexes. The adsorption of the complexes on the surface of Ag@SiO2 nanoparticles was confirmed by transmission electron microscope and energy dispersive X-ray spectroscopy. Luminescence property investigation showed that the factors affecting the MEL effect included the excitation and emission wavelength of lanthanide complexes, the kinds of lanthanide ions and organic ligands, as well as the core size and shell thickness of Ag@SiO2. Among these factors, the excitation wavelength of lanthanide complexes and the SiO2 shell thickness were found to play decisive roles. Finally, 25.92 times enhancement in luminescent intensity and 7.4 times increase in luminescence quantum yield can be achieved on Tb(BA)(3)center dot H2O by Ag@SiO2 with core size of 46 nm and shell thickness of 24 nm.
About Pyrazine-2-carboxylic acid, If you have any questions, you can contact Zhao, YF; Wang, AL; Kang, J; Chu, HB; Zhang, HX; Zhao, YL or concate me.. Quality Control of Pyrazine-2-carboxylic acid
Reference:
Patent; Chevron Research Company; US4732894; (1988); A;,
Pyrazine – Wikipedia,
Pyrazine | C4H4N2 – PubChem