Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 123-32-0, Name is 2,5-Dimethylpyrazine, SMILES is C1=NC(=CN=C1C)C, in an article , author is Wang, Dan, once mentioned of 123-32-0, Safety of 2,5-Dimethylpyrazine.
The 3D POMOFs based two As-III-capped Keggin arsenomolybdates with four V-IV substituted: Synthesis, structures and properties
A novel 3D POMOFs based As-III-capped Keggin arsenomolybdate with four V-IV substituted, [(As2AsMO8V4O40)-As-III-M-V-V-VI-O-IV](2)[(CuCu2II)-Cu-I(pz)(4)](2)center dot 9H(2)O (1) (pz = pyrazine) was prepared by hydrothermal method and characterized by elemental analysis, IR, TG, XPS, BET, Raman, optical band gap and XRD. Compound 1 represents the first polyoxometalate metal organic frameworks (POMOFs) based [(As2AsMO8V4O40)-As-III-M-V-V-VI-O-IV](5-) polyoxoanion and {Cu-pz} complex, which forms a 3D topological network with the Schlafli symbol of {5.6.8}{5(2).6.7.8(2)}{5(2).7(2).8(2)}{6.7.8}. Compound 1 displays excellent photocatalytic activity and stability for degradation methylene blue (MB), rhodamine-B (RhB), methyl orange (MO), and Azophloxine (AP) under UV light. The photodegradation reaction kinetic and mechanism of 1 were explored. In addition, the luminescence property of 1 was also investigated.
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