Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Widera, Anna, once mentioned the application of 2847-30-5, Name is 2-Methoxy-3-methylpyrazine, molecular formula is C6H8N2O, molecular weight is 124.1405, MDL number is MFCD00006127, category is Pyrazines. Now introduce a scientific discovery about this category, Quality Control of 2-Methoxy-3-methylpyrazine.
Electron-Rich, Lewis Acidic Diborane Meets N-Heterocyclic Aromatics: Formation and Electron Transfer in Cyclophane Boranes
Herein reported are the reactions of an electron-rich, Lewis acidic diborane with N-heterocyclic aromatics to give first members of an unprecedented family of highly charged cationic cyclophanes with diboranyl units. Tetracationic cyclophanes with 4,4′-bipyridine/ 1,2-bis(4-pyridyl)ethylene and diboranyl units were synthesized and their redox chemistry was studied. Cyclisation of two diboranyl and two pyrazine units is accompanied by electron transfer from the diboranyl unit to the pyrazine. Our results pave the way for the integration of redox-active diboranyl units into cyclophanes and supramolecular structures.
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